Shall I create a new account if I want to be a DropShipper in Alibaba.com?

Kindly note that you will need to have both account in Alibaba.com and account in Independent Service Vendors, like Woocommerce.

Regarding account in Alibaba.com:

If you have registered in Alibaba.com, you may log in the account and manage your dropshipping information in Alibaba.com.

If you have not registered any account in Alibaba.com yet, please click Join Free here and create a new account.

Regarding account in in-Independent Service Vendors, like Woocommerce: please make sure you've created an account in the website before you want to do start your DropShipping business in Alibaba.com.